Title of video: "Learning differences: Effective teaching with learning styles and multiple intelligences programs 9-12"

Title of chapter: "The hook and hold strategy: anticipatory set"

Since the APA Publication Manual does not address what to do when a video is divided up into distinct sections, you could start drawing parallels to other citations that are similar, for example a "single episode in a television series", where both the series name and episode name are given in the citation. However, we would recommend that instead of inventing new rules that may or may not be right, you should cite the recording as a whole, then refer to the specific part in the text of your paper. So your citation would be:

Learning differences: Effective teaching with learning styles and multiple intelligences programs 9-12 [Motion picture]. (2002). United States: Walden University.

The in-text citation would be:

...and in "The hook and hold strategy: anticipatory set," we find that blah blah blah (Learning, 2002).